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Standard enthalpy of formation of dichloroiodine(III) tetrachloroaluminium(III), [ICl2(+)][AlCl4(-)] and the thermochemistry and energetics of the gaseous dichloroiodine(III) cation, [ICl2(+)]
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UNSPECIFIED (1997) Standard enthalpy of formation of dichloroiodine(III) tetrachloroaluminium(III), [ICl2(+)][AlCl4(-)] and the thermochemistry and energetics of the gaseous dichloroiodine(III) cation, [ICl2(+)]. POLYHEDRON, 16 (20). pp. 3571-3575. ISSN 0277-5387.
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Abstract
The experimental determination of the standard enthalpy of formation of the crystalline salt [ICI2+][AlCl4-], is reported to be Delta(f)H(0)(IAlCl6,c)/kJ mol(-1) = -836.6 +/- 6.2 along with the total lattice potential energy, U-POT(IAlCl6)/kJ mol(-1), calculated to be 562.5 +/- 5.0 using the program LATEN. The standard enthalpy of formation of the [ICI2+] cation, Delta(f)H(0) ([ICI2+],g)/kJ mol(-1) is found to be 926.9 +/- 9.0. The electron attachment enthalpies for the ICI2 (g) and [ICI2+] (g) species, are in kJ mol(-1) : 533.2 and -999, respectively. (C) 1997 Elsevier Science Ltd.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | POLYHEDRON | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0277-5387 | ||||
Official Date: | 1997 | ||||
Dates: |
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Volume: | 16 | ||||
Number: | 20 | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 3571-3575 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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