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Local structure of NH2 on Si(100)-(2x1) and its effect on the asymmetry of the Si surface dimers

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UNSPECIFIED (1997) Local structure of NH2 on Si(100)-(2x1) and its effect on the asymmetry of the Si surface dimers. PHYSICAL REVIEW LETTERS, 79 (4). pp. 673-676. ISSN 0031-9007

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Abstract

A scanned-energy mode photoelectron diffraction study of the Si(100)-(2 x 1) surface with adsorbed NH2 provides quantitative determination of key structural parameters previously only predicted from theoretical calculations. In particular, the N atoms occupy off-atop sites at a dimerized surface Si atom with N-Si bond lengths of 1.73 +/- 0.08 Angstrom and bond angle relative to the surface normal of 21 degrees +/- 4 degrees. The adsorption greatly reduces the Si dimer asymmetry relative to that of the clean surface.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Journal or Publication Title: PHYSICAL REVIEW LETTERS
Publisher: AMERICAN PHYSICAL SOC
ISSN: 0031-9007
Date: 28 July 1997
Volume: 79
Number: 4
Number of Pages: 4
Page Range: pp. 673-676
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/16535

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