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Synthesis and characterization of magnetoelectric Ba7Mn4O15
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Clarke, Gabriel R. M., Lees, Martin R., Ritter, Clemens, da Silva, Ivan and Senn, Mark S. (2022) Synthesis and characterization of magnetoelectric Ba7Mn4O15. Inorganic Chemistry, 61 (26). pp. 10015-10022. doi:10.1021/acs.inorgchem.2c00889 ISSN 0020-1669.
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WRAP-synthesis-characterization-magnetoelectric-Ba7Mn4O15-Senn-2022.pdf - Published Version - Requires a PDF viewer. Available under License Creative Commons Attribution 4.0. Download (4086Kb) | Preview |
Official URL: https://doi.org/10.1021/acs.inorgchem.2c00889
Abstract
We present the synthesis of a novel binary metal oxide material: Ba7Mn4O15. The crystal structure has been investigated by high-resolution powder synchrotron X-ray diffraction in the temperature range of 100–300 K as well as by powder neutron diffraction at 10 and 80 K. This material represents an isostructural barium-substituted analogue of the layered material Sr7Mn4O15 that forms its own structural class. However, we find that Ba7Mn4O15 adopts a distinct magnetic ordering, resulting in a magnetoelectric ground state below 50 K. The likely magnetoelectric coupling mechanisms have been inferred from performing a careful symmetry-adapted refinement against the powder neutron diffraction experiments, as well as by making a comparison with the nonmagnetoelectric ground state of Sr7Mn4O15.
| Item Type: | Journal Article | |||||||||||||||
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| Subjects: | Q Science > QD Chemistry | |||||||||||||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||||||||
| SWORD Depositor: | Library Publications Router | |||||||||||||||
| Library of Congress Subject Headings (LCSH): | Metallic oxides , Metallic oxides -- Electric properties, Metallic oxides -- Magnetic properties, Solid state chemistry | |||||||||||||||
| Journal or Publication Title: | Inorganic Chemistry | |||||||||||||||
| Publisher: | American Chemical Society | |||||||||||||||
| ISSN: | 0020-1669 | |||||||||||||||
| Official Date: | 21 June 2022 | |||||||||||||||
| Dates: |
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| Volume: | 61 | |||||||||||||||
| Number: | 26 | |||||||||||||||
| Page Range: | pp. 10015-10022 | |||||||||||||||
| DOI: | 10.1021/acs.inorgchem.2c00889 | |||||||||||||||
| Status: | Peer Reviewed | |||||||||||||||
| Publication Status: | Published | |||||||||||||||
| Access rights to Published version: | Open Access (Creative Commons) | |||||||||||||||
| Date of first compliant deposit: | 18 July 2022 | |||||||||||||||
| Date of first compliant Open Access: | 19 July 2022 | |||||||||||||||
| RIOXX Funder/Project Grant: |
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