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Photocontrolled nucleobase binding to an organometallic Ru-II arene complex

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Betanzos-Lara, Soledad, Salassa, Luca, Habtemariam, Abraha and Sadler, P. J. (2009) Photocontrolled nucleobase binding to an organometallic Ru-II arene complex. Chemical Communications (No.43). pp. 6622-6624. doi:10.1039/b914153g ISSN 1359-7345.

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Official URL: http://dx.doi.org/10.1039/b914153g

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Abstract

The complex [(p-cym)Ru(bpm)(py)][PF6](2) (where p-cym = para-cymene, bpm = 2,2'-bipyrimidine and py = pyridine) is the first ruthenium(II) arene complex that can selectively photodissociate a monodentate ligand (py) when excited with visible light and form a reactive aqua derivative able to bind to a DNA base.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QP Physiology
R Medicine > RS Pharmacy and materia medica
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH): Ruthenium compounds -- Therapeutic use, Aromatic compounds -- Therapeutic use, Organometallic compounds -- Therapeutic use, Antineoplastic agents, DNA-ligand interactions, Photochemistry
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 21 November 2009
Dates:
DateEvent
21 November 2009Published
Number: No.43
Number of Pages: 3
Page Range: pp. 6622-6624
DOI: 10.1039/b914153g
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Consejo Nacional de Ciencia y Tecnología (Mexico) (CONACYT), Seventh Framework Programme (European Commission) (FP7), European Regional Development Fund (ERDF), Advantage West Midlands (AWM), Overseas Research Students Awards Scheme (ORSAS)
Grant number: 220281 (FP7)

Data sourced from Thomson Reuters' Web of Knowledge

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