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Data for Synthesis of a nanoscale Cu(II)31-oxo-carboxylate cluster, and effect of Cu-oxo cluster size on visible-light absorption
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Barnes, Thomas J., Payne, Jack and Pike, Sebastian D. (2022) Data for Synthesis of a nanoscale Cu(II)31-oxo-carboxylate cluster, and effect of Cu-oxo cluster size on visible-light absorption. [Dataset]
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Dataset to support article Synthesis of a nanoscale Cu(II)31-oxo-carboxylate cluster. and effect of Cu-oxo cluster size on visible-light absorption.zip - Published Version Available under License Creative Commons Attribution 4.0. Download (1002Kb) |
Official URL: https://doi.org/10.1039/D2CC05478G
Abstract
Cu16–Cu31 Cu(II)-oxo-carboxylate clusters are reported, including those with condensed 1.5 nm Cu–O cores supported exclusively by O-donor ligands. A size–colour correlation is observed due to a red-shift of the charge transfer absorption band on increasing size; hence these clusters sit between small molecules and (black) CuO nanostructures.
| Item Type: | Dataset | ||||||||||||
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| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||||
| Publisher: | University of Warwick, Department of Chemistry | ||||||||||||
| Official Date: | 7 December 2022 | ||||||||||||
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| Status: | Not Peer Reviewed | ||||||||||||
| Publication Status: | Published | ||||||||||||
| Media of Output (format): | Excel (XLSX) and Origin (opju) files | ||||||||||||
| Access rights to Published version: | Open Access (Creative Commons) | ||||||||||||
| Copyright Holders: | University of Warwick | ||||||||||||
| Date of first compliant deposit: | 7 December 2022 | ||||||||||||
| Date of first compliant Open Access: | 7 December 2022 | ||||||||||||
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