Emerson-King, Jack, Pan, Sudip, Gyton, Matthew R., Tonner-Zech, Ralf and Chaplin, Adrian B. (2023) Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand. Chemical Communications . doi:10.1039/D2CC06837K ISSN 1359-7345. (In Press)

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Abstract

The synthesis and characterisation of the rhodium(III) dinitrogen complex [Rh(2,2’-biphenyl)(CxP2)(N2)]+ are described, where CxP2 is a trans-spanning calix[4]arene-based diphosphine and the dinitrogen ligand is projected into the cavity of the macrocycle.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH):	Chemistry, Inorganic, Nitrogen -- Fixation, Transition metals
Journal or Publication Title:	Chemical Communications
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Official Date:	23 January 2023
Dates:	Date Event 23 January 2023 Available 23 January 2023 Accepted
DOI:	10.1039/D2CC06837K
Status:	Peer Reviewed
Publication Status:	In Press
Access rights to Published version:	Open Access (Creative Commons)
Date of first compliant deposit:	24 January 2023
Date of first compliant Open Access:	25 January 2023
RIOXX Funder/Project Grant:	Project/Grant ID RIOXX Funder Name Funder ID 637313 European Research Council http://dx.doi.org/10.13039/501100000781 UF100592 [RS] Royal Society http://dx.doi.org/10.13039/501100000288 UF150675 [RS] Royal Society http://dx.doi.org/10.13039/501100000288

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