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Shallow donor state of hydrogen in In2O3 and SnO2: implications for conductivity in transparent conducting oxides

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King, P. D. C., Lichti, R. L., Celebi, Y. G., Gil, J. M., Vilao, R. C., Alberto, H. V., Duarte, J. Piroto, Payne, D. J., Egdell, R. G., McKenzie, I., McConville, C. F. (Chris F.), Cox, S. F. J. and Veal, T. D. (Tim D.) (2009) Shallow donor state of hydrogen in In2O3 and SnO2: implications for conductivity in transparent conducting oxides. Physical Review B (Condensed Matter and Materials Physics), Vol.80 (No.8). Article no. 081201(R). doi:10.1103/PhysRevB.80.081201

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Official URL: http://dx.doi.org/10.1103/PhysRevB.80.081201

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Abstract

Muonium, and by analogy hydrogen, is shown to form a shallow-donor state in In2O3 and SnO2. The paramagnetic charge state is stable below similar to 50 K in In2O3 and similar to 30 K in SnO2 which, coupled with its extremely small effective hyperfine splitting in both cases, allows its identification as the shallow-donor state. This has important implications for the controversial issue of the origins of conductivity in transparent conducting oxides.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Divisions: Faculty of Science > Physics
Journal or Publication Title: Physical Review B (Condensed Matter and Materials Physics)
Publisher: American Physical Society
ISSN: 1098-0121
Official Date: August 2009
Dates:
DateEvent
August 2009Published
Volume: Vol.80
Number: No.8
Number of Pages: 4
Page Range: Article no. 081201(R)
DOI: 10.1103/PhysRevB.80.081201
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Funder: Engineering and Physical Sciences Research Council (EPSRC), National Science Foundation (U.S.) (NSF), R. A. Welch Foundation, Science and Technology Facilities Council (Great Britain) (STFC)
Grant number: EP/G004447/1 (EPSRC), DMR-0604501, D-1321

Data sourced from Thomson Reuters' Web of Knowledge

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