Dielectric relaxation spectroscopy of a poly-beta-hydroxybutyrate homopolymer
UNSPECIFIED (1997) Dielectric relaxation spectroscopy of a poly-beta-hydroxybutyrate homopolymer. EUROPEAN POLYMER JOURNAL, 33 (6). pp. 857-861. ISSN 0014-3057Full text not available from this repository.
Contour maps of complex relative permittivity for a commercial poly-beta-hydroxybutyrate homopolymer reveal four distinct loss regions within 0.1-3 MHz and -17 to +145 degrees C. The losses are attributed, respectively, to carbonyl-driven local mode beta-relaxations involving methyl and ester groups, to the alpha-process associated with the glass transition, to an MWS polarisation process, and to the presence of phosphite residues. There are indications of a further individual loss associated with crystalline softening or melting. (C) 1997 Elsevier Science Ltd.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||EUROPEAN POLYMER JOURNAL|
|Publisher:||PERGAMON-ELSEVIER SCIENCE LTD|
|Number of Pages:||5|
|Page Range:||pp. 857-861|
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