The catalytic activity of xanthine oxidase: Mechanistic insights through computer modelling
UNSPECIFIED (1997) The catalytic activity of xanthine oxidase: Mechanistic insights through computer modelling. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (8). pp. 1267-1268. ISSN 0300-9246Full text not available from this repository.
The catalytic cycle for substrate oxidation at the molybdenum centre of xanthine oxidase has been modelled with density functional theory; using our previously developed active-site model plus formaldehyde as substrate, the structures and relative energies of intermediate and transition-state species have been employed to examine the key issues of active-site conformation, the role of Mo-C interactions and the identity of the transferred oxygen.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS|
|Publisher:||ROYAL SOC CHEMISTRY|
|Date:||21 April 1997|
|Number of Pages:||2|
|Page Range:||pp. 1267-1268|
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