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Metallacycles of the imidoylamidinato compounds HNC(R)NC(R)NH and Group 13 elements. Crystal structure of the complex [GaMe(2){HNC(CF3)NC(CF3)NH}]
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UNSPECIFIED (1997) Metallacycles of the imidoylamidinato compounds HNC(R)NC(R)NH and Group 13 elements. Crystal structure of the complex [GaMe(2){HNC(CF3)NC(CF3)NH}]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (6). pp. 909-910. ISSN 0300-9246
Full text not available from this repository.Abstract
Reaction of trimethylgallium with trifluoroacetamidine [H2NC(CF3)NH] resulted in an unusual elimination reaction, and yielded the air-stable volatile metallacycle [GaMe(2){HNC(CF3)NC(CF3)NH}] which shows a planar six-membered (GaNCNCN) ring; a related aluminium system. [AlMe(2){HNC(Ph)NC(Ph)NH}] was formed using benzamidine [H2NC(Ph)NH].
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 0300-9246 |
| Date: | 21 March 1997 |
| Number: | 6 |
| Number of Pages: | 2 |
| Page Range: | pp. 909-910 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/17881 |
Data sourced from Thomson Reuters' Web of Knowledge
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