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Synthesis of methacrylic multi-arm star copolymers by ''arm-first'' group transfer polymerisation
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UNSPECIFIED (1997) Synthesis of methacrylic multi-arm star copolymers by ''arm-first'' group transfer polymerisation. MACROMOLECULAR CHEMISTRY AND PHYSICS, 198 (3). pp. 871-881. ISSN 1022-1352
Full text not available from this repository.Abstract
Methacrylic star polymers were synthesized by the ''arm-first'' method of star polymer formation by the addition of difunctional monomer, ethylene glycol dimethacrylate, to living linear poly(methyl methacrylate) as prepared by group transfer polymerisation (GTP). The effects of living polymer concentration and ratio of difunctional monomer to living polymer are discussed, and show how macromolecular design and control may be imposed on the number of arms and molecular weight of the star polymer. Diluting the difunctional crosslinking monomer with monomer has been examined with the view to establishing funtionalisation of the star core.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | MACROMOLECULAR CHEMISTRY AND PHYSICS |
| Publisher: | HUTHIG & WEPF VERLAG |
| ISSN: | 1022-1352 |
| Date: | March 1997 |
| Volume: | 198 |
| Number: | 3 |
| Number of Pages: | 11 |
| Page Range: | pp. 871-881 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/17935 |
Data sourced from Thomson Reuters' Web of Knowledge
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