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Structural characterization of the acetonitrile complex NbCl5(MeCN)
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UNSPECIFIED (1997) Structural characterization of the acetonitrile complex NbCl5(MeCN). POLYHEDRON, 16 (3). pp. 351-353. ISSN 0277-5387
Full text not available from this repository.Abstract
The monosolvate (MeCN) of niobium(V) chloride has been structurally characterized. The metal is six coordinate with a somewhat distorted octahedral geometry in which the four equatorial chlorine atoms are coplanar but are clearly bent towards the bound axial acetonitrile ligand, mean N-ax-Nb-Cl-eq 83.62(12). The Nb-Cl bond distances lie in the range 2.249(2)-2.319(2) Angstrom and the metal to ligand distance, Nb-N, is 2.236(4) Angstrom. Copyright (C) 1996 Elsevier Science Ltd
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | POLYHEDRON |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| ISSN: | 0277-5387 |
| Date: | 1997 |
| Volume: | 16 |
| Number: | 3 |
| Number of Pages: | 3 |
| Page Range: | pp. 351-353 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/18159 |
Data sourced from Thomson Reuters' Web of Knowledge
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