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Aqueous vanadosilicates
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UNSPECIFIED (1996) Aqueous vanadosilicates. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (22). pp. 4189-4192. ISSN 0300-9246
Full text not available from this repository.Abstract
Silicate anions were shown by V-51 and O-17 NMR spectroscopy to combine with aqueous [HVO4](2-) in aqueous alkaline solution, forming the anions [H2VSiO7](3-), [H3VSiO7](2-) and various related monovanadooligosilicate species. Approximate equilibrium constants have been derived; and shown to depend only weakly upon ionic strength. The ion [H2VSiO7](3-) at higher concentrations also dimerises to give an anion with a SiOVOVOSi linkage, as shown by selective inversion-transfer subtraction spectra.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 0300-9246 |
| Date: | 21 November 1996 |
| Number: | 22 |
| Number of Pages: | 4 |
| Page Range: | pp. 4189-4192 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/18183 |
Data sourced from Thomson Reuters' Web of Knowledge
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