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An X-ray diffraction and NMR study into the mechanism of zircon formation from aqueous sols

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UNSPECIFIED (1996) An X-ray diffraction and NMR study into the mechanism of zircon formation from aqueous sols. JOURNAL OF MATERIALS SCIENCE, 31 (22). pp. 5873-5876. ISSN 0022-2461

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Abstract

Solid solutions of the formula Zr1-xSixO2 (x=0-0.5) were produced by an aqueous inorganic set-gel route. X-ray diffraction and solid state magic-angle spinning-nuclear magnetic resonance (MAS-NMR) were used to characterize the products at various calcination temperatures. The solubility limit of silica in zirconia at <950 degrees C was found to be similar to x=0.15 and that this amount stabilized the tetragonal zirconia phase to higher temperatures and inhibited the formation of zircon. With x=0.5, zircon formation was 70% at only 1100 degrees C.

Item Type: Journal Article
Subjects: T Technology > TA Engineering (General). Civil engineering (General)
Journal or Publication Title: JOURNAL OF MATERIALS SCIENCE
Publisher: CHAPMAN HALL LTD
ISSN: 0022-2461
Date: 15 November 1996
Volume: 31
Number: 22
Number of Pages: 4
Page Range: pp. 5873-5876
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/18198

Data sourced from Thomson Reuters' Web of Knowledge

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