UNSPECIFIED (1996) Enantioselective dioxygenase-catalysed formation and thermal racemisation of chiral thiophene sulfoxides. CHEMICAL COMMUNICATIONS (20). pp. 2363-2364. ISSN 1359-7345

Full text not available from this repository.

Abstract

Substituted chiral thiophene 1-oxides and their cycloadducts of variable enantiopurity have been isolated as products of dioxygenase-catalysed sulfoxidation of the corresponding thiophenes using intact cells of Pseudomonas putida; thermal racemization (Delta G(double dagger) = 25.1 kcal mol(-1)) of the enantiopure metabolite (1R)-2-methylbenzo[b]thiophene 1-oxide has been observed.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Journal or Publication Title:	CHEMICAL COMMUNICATIONS
Publisher:	ROYAL SOC CHEMISTRY
ISSN:	1359-7345
Date:	21 October 1996
Number:	20
Number of Pages:	2
Page Range:	pp. 2363-2364
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/18283

Data sourced from Thomson Reuters' Web of Knowledge

Request changes to a record

Actions (login required)

View Item