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Enantioselective dioxygenase-catalysed formation and thermal racemisation of chiral thiophene sulfoxides
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UNSPECIFIED (1996) Enantioselective dioxygenase-catalysed formation and thermal racemisation of chiral thiophene sulfoxides. CHEMICAL COMMUNICATIONS (20). pp. 2363-2364. ISSN 1359-7345.
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Abstract
Substituted chiral thiophene 1-oxides and their cycloadducts of variable enantiopurity have been isolated as products of dioxygenase-catalysed sulfoxidation of the corresponding thiophenes using intact cells of Pseudomonas putida; thermal racemization (Delta G(double dagger) = 25.1 kcal mol(-1)) of the enantiopure metabolite (1R)-2-methylbenzo[b]thiophene 1-oxide has been observed.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 21 October 1996 | ||||
Dates: |
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Number: | 20 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 2363-2364 | ||||
Publication Status: | Published |
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