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Low-temperature synthesis and characterization of ceria-based oxide ion conductors

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UNSPECIFIED (1996) Low-temperature synthesis and characterization of ceria-based oxide ion conductors. JOURNAL OF MATERIALS SCIENCE, 31 (19). pp. 5005-5007. ISSN 0022-2461

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Abstract

Solid solutions of the general formula Ce(1-x)Ln(x)O(2-x/2) square(x/2) (Ln = lanthanide (III) and square = anion vacancy), were prepared by a novel sol-gel route. These materials were characterized by powder diffraction and scanning electron microscopy. The gels formed on sol evaporation were found to be solid solutions with the fluorite structure and a crystallite size of approximately 6 nm. This is the lowest temperature of formation to date. The gels densified readily at 700 degrees C and the lattice parameter of these materials was found to be directly proportional to the ionic radius of the dopant.

Item Type: Journal Article
Subjects: T Technology > TA Engineering (General). Civil engineering (General)
Journal or Publication Title: JOURNAL OF MATERIALS SCIENCE
Publisher: CHAPMAN HALL LTD
ISSN: 0022-2461
Date: 1 October 1996
Volume: 31
Number: 19
Number of Pages: 3
Page Range: pp. 5005-5007
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/18337

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