Oxygen-induced step-edge faceting; A precursor to (410) planar faceting of Cu(100) vicinal surfaces
UNSPECIFIED (1996) Oxygen-induced step-edge faceting; A precursor to (410) planar faceting of Cu(100) vicinal surfaces. CHEMICAL PHYSICS LETTERS, 259 (5-6). pp. 503-507. ISSN 0009-2614Full text not available from this repository.
Scanning tunneling microscopy has been applied to an atomistic scale investigation of the oxygen-induced restructuring of a Cu(100) vicinal surface, close to (610) but with average step orientations 10 degrees away from . The initial changes upon oxygen adsorption are found to be step-edge faceting to  and , and  step coalescence to form small (410) facets. Annealing enlarges these (410) facets while the much shorter  steps coalesce to form (401) facets. The implied strong energetic favouring of (100) step-edges in the presence of oxygen is attributed to the formation of Cu-O-Cu-O linear chains, known to be the stable element of oxygen-induced reconstruction of the (110) and (100) copper surfaces.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry
Q Science > QC Physics
|Journal or Publication Title:||CHEMICAL PHYSICS LETTERS|
|Publisher:||ELSEVIER SCIENCE BV|
|Date:||13 September 1996|
|Number of Pages:||5|
|Page Range:||pp. 503-507|
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