Aqueous tungstovanadate equilibria
UNSPECIFIED (1996) Aqueous tungstovanadate equilibria. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (13). pp. 2705-2711. ISSN 0300-9246Full text not available from this repository.
A combined equilibrium study of tungstovanadates involving potentiometry and V-51, W-183 and O-17 NMR spectroscopy has been able to identify 11 main species, giving their formation Constants and pK(a) values where relevant. Tentative identification was also made of two other non-equilibrium species at lower pH values, in addition to those with a V-centred Keggin structure. The V-51 shifts of the unprotonated hexametalate anions fall into a rational pattern, and the formation constants are all higher than those of the corresponding molybdovanadate species, where comparisons are possible.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS|
|Publisher:||ROYAL SOC CHEMISTRY|
|Date:||7 July 1996|
|Number of Pages:||7|
|Page Range:||pp. 2705-2711|
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