UNSPECIFIED (1996) Structures of the multireceptor vaulted cyclidene complexes. Inorganica Chimica Acta, 246 (1-2). pp. 109-118. ISSN 0020-1693

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Abstract

The preparations and structures of three vaulted cyclidene complexes are compared with the two previously reported. All show similar structures with large rigid cavities partly closed off by the piperidine risers, illustrating in particular the attractive effect of van der Waals forces resulting in the incorporation of solvent molecules or [PF6](-) ions nesting on the edges of the cavities. However, the detailed geometries vary, according to the nature of the ligand substituents, the metal, the counter-ion and the lattice solvent molecules. These give rise to differing orientations of the capping aromatic rings and the piperidine risers.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Journal or Publication Title:	Inorganica Chimica Acta
Publisher:	ELSEVIER SCIENCE SA LAUSANNE
ISSN:	0020-1693
Date:	May 1996
Volume:	246
Number:	1-2
Number of Pages:	10
Page Range:	pp. 109-118
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/18732

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