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A copper(II) complex of a macrocyclic Schiff base ligand with a polyether bridge
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UNSPECIFIED (1996) A copper(II) complex of a macrocyclic Schiff base ligand with a polyether bridge. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 52 (Part 5). pp. 1134-1136. ISSN 0108-2701
Full text not available from this repository.Abstract
In the structure of aquachloro[7,10,13-trioxa-3,17,23-triazabicyclo[17.3.1]tricosa-1 (23),2,17,19,21-pentaene-N,N',N '']copper(II) hexafluorophosphate acetonitrile solvate, the Cu-II ion is pentacoordinate with square-pyramidal coordination geometry, with a relatively long axial bond to water [2.244 (5) Angstrom] and with the shortest Cu-N bond being to the pyridine N atom. The water molecule is also hydrogen bonded to two O atoms of the ligand. the complex is folded about the N-Cu-N axis, the polyether chain being nearly planar and making an angle of about 135 degrees with the pyridine ring.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS |
| Publisher: | MUNKSGAARD INT PUBL LTD |
| ISSN: | 0108-2701 |
| Date: | 15 May 1996 |
| Volume: | 52 |
| Number: | Part 5 |
| Number of Pages: | 3 |
| Page Range: | pp. 1134-1136 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/18772 |
Data sourced from Thomson Reuters' Web of Knowledge
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