Electrical characterization of spherical Ln(2)Zr(2)O(7) (Ln=La, Nd, Dy) prepared via a low temperature sol-gel route
UNSPECIFIED. (1996) Electrical characterization of spherical Ln(2)Zr(2)O(7) (Ln=La, Nd, Dy) prepared via a low temperature sol-gel route. EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY, 33 (5). pp. 441-452. ISSN 0992-4361Full text not available from this repository.
Spherical particles of lanthanide zirconates Ln(2)Zr(2)O(7) (Ln=La,Nd,Dy) were prepared by an aqueous inorganic sol-gel route. Characterisation was by X-ray diffraction, scanning electron microscopy, differential thermal analysis, thermogravimetric analysis and complex impedance spectroscopy. Calcination of the gel spheres at 750 degrees C produced fully crystalline fluorite phases. Further calcination above 850 degrees C produced pyrochlore phases with La and Nd. Activation energies and pre-exponential factors were calculated from complex impedance curves obtained in the temperatures range 570-1000K.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY|
|Number of Pages:||12|
|Page Range:||pp. 441-452|
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