UNSPECIFIED (1996) Synthesis of polyester dendrimers. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (7). pp. 649-656. ISSN 0300-922X

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Abstract

Phloroglucinol 4, hydroquinone 5 and naphthalene-2,6-diol 6 react with the monomer 2, activated either by 1,3-dicyclohexylcarbodiimide (DCC) or as its acid, chloride 3. Hydrogenolysis of the benzyl protecting groups, followed by repetition of these procedures leads, divergently, to three series of analytically pure aryl polyester dendrimers in high yields. The de Gennes limit appears to lie between generations three and four with the three-branched initiator core 4 and between generations four and five with the two-branched cores 5 and 6.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Journal or Publication Title:	JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Publisher:	ROYAL SOC CHEMISTRY
ISSN:	0300-922X
Date:	7 April 1996
Number:	7
Number of Pages:	8
Page Range:	pp. 649-656
Publication Status:	Published
URI:	http://wrap.warwick.ac.uk/id/eprint/18913

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