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Halide abstraction as a route to cationic molybdenum(IV) compounds: Crystal and molecular structure of [CpMoCl(MeCN)(4)][SbCl6](2)center dot MeCN
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UNSPECIFIED (1996) Halide abstraction as a route to cationic molybdenum(IV) compounds: Crystal and molecular structure of [CpMoCl(MeCN)(4)][SbCl6](2)center dot MeCN. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 510 (1-2). pp. 213-217. ISSN 0022-328X
Full text not available from this repository.Abstract
Treatment of CpMoCl(3)(MeCN)(2) with SbCl5 in acetonitrile solution provides the solvated cationic series [CpMoCl(2)(MeCN)(3)](+), [CpMoCl(MeCN)(4)](2+) and [CpMo(MeCN)(6)](3+) as hexachloroantimon(v)ate salts following sequential halide abstraction. Characterization follows from microanalytical and spectroscopic (IR, and H-1 NMR) data and, in the case of [CpMoCl(MeCN)(4)][SbCl6](2) . MeCN, by X-ray crystallographic studies. The structure is disordered but individual cations contain a six coordinated pseudo-octahedral metal geometry in which the cyclopentadienyl ligand (regarded as unidentate) and the chlorine atom occupy axial positions with an equatorial array of four acetonitrile ligands.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY |
| Publisher: | ELSEVIER SCIENCE SA LAUSANNE |
| ISSN: | 0022-328X |
| Date: | 21 March 1996 |
| Volume: | 510 |
| Number: | 1-2 |
| Number of Pages: | 5 |
| Page Range: | pp. 213-217 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/18918 |
Data sourced from Thomson Reuters' Web of Knowledge
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