Halide abstraction as a route to cationic molybdenum(IV) compounds: Crystal and molecular structure of [CpMoCl(MeCN)(4)][SbCl6](2)center dot MeCN
UNSPECIFIED (1996) Halide abstraction as a route to cationic molybdenum(IV) compounds: Crystal and molecular structure of [CpMoCl(MeCN)(4)][SbCl6](2)center dot MeCN. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 510 (1-2). pp. 213-217. ISSN 0022-328XFull text not available from this repository.
Treatment of CpMoCl(3)(MeCN)(2) with SbCl5 in acetonitrile solution provides the solvated cationic series [CpMoCl(2)(MeCN)(3)](+), [CpMoCl(MeCN)(4)](2+) and [CpMo(MeCN)(6)](3+) as hexachloroantimon(v)ate salts following sequential halide abstraction. Characterization follows from microanalytical and spectroscopic (IR, and H-1 NMR) data and, in the case of [CpMoCl(MeCN)(4)][SbCl6](2) . MeCN, by X-ray crystallographic studies. The structure is disordered but individual cations contain a six coordinated pseudo-octahedral metal geometry in which the cyclopentadienyl ligand (regarded as unidentate) and the chlorine atom occupy axial positions with an equatorial array of four acetonitrile ligands.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||JOURNAL OF ORGANOMETALLIC CHEMISTRY|
|Publisher:||ELSEVIER SCIENCE SA LAUSANNE|
|Date:||21 March 1996|
|Number of Pages:||5|
|Page Range:||pp. 213-217|
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