The potential of sulfimides as chiral acyl anion equivalents
UNSPECIFIED. (1996) The potential of sulfimides as chiral acyl anion equivalents. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (4). pp. 313-317. ISSN 0300-922XFull text not available from this repository.
Reaction of the tosyl imides 6 and 8 of 1,3-dithiane and 1,3,5-trithiane with sodium hydride and alkyl iodides in DMF yields anti alkylated products in all cases, In the case of the trithiane imide 8, both mono- and di-alkylation is observed, Preparation of cyclic sulfimide analogues of Eliel's oxathiane is shown to be problematic, but a new class of O,S-acetals, namely 4-bromophenylthiomethyl (BPTM) ethers, is introduced as a replacement for their troublesome phenylthiomethyl (PTM) analogues.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1|
|Publisher:||ROYAL SOC CHEMISTRY|
|Official Date:||21 February 1996|
|Number of Pages:||5|
|Page Range:||pp. 313-317|
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