Synthesis of styryl tetrahydrofurans and tetrahydropyrans via addition of radicals to unsaturated sulfimides.
UNSPECIFIED (1996) Synthesis of styryl tetrahydrofurans and tetrahydropyrans via addition of radicals to unsaturated sulfimides. TETRAHEDRON LETTERS, 37 (6). pp. 909-912. ISSN 0040-4039Full text not available from this repository.
The addition of tetrahydrofuranyl or tetrahydropyranyl radicals to (E)-styryl sulfimide derivatives furnishes the corresponding (E)-styryl tetrahydrofurans or tetrahydropyrans respectively. The corresponding radical reactions with (Z)-styryl sulfimides gives rise to a mixture of (E) and (Z) isomers, this is in contrast to the Et(3)B mediated reaction, which is stereoselective.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||TETRAHEDRON LETTERS|
|Publisher:||PERGAMON-ELSEVIER SCIENCE LTD|
|Date:||5 February 1996|
|Number of Pages:||4|
|Page Range:||pp. 909-912|
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