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LIGATED LANTHANIDE CLUSTERS IN THE FAST-ATOM-BOMBARDMENT OF LANTHANIDE CARBOXYLATES
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UNSPECIFIED (1995) LIGATED LANTHANIDE CLUSTERS IN THE FAST-ATOM-BOMBARDMENT OF LANTHANIDE CARBOXYLATES. Inorganica Chimica Acta, 238 (1-2). pp. 109-114. ISSN 0020-1693.
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Abstract
The fast atom bombardment (FAB) of acetates and malonates of lanthanides (Ln) reveals clustering as a result of ion - molecule reactions to give in the general case the ion [(LnO)(x)(RCO(2))(y)O-z](+) with x reaching 4, y reaching 3 and z reaching 4. Binary clusters [(LnO)(x)O-y](+) are also found, with x reaching high values. Ligand fragmentation occurs both in these series and also with complexes of Ln with glycine and mono- and trichloroacetate ions. Certain combinations of x, y and tare associated with markedly high levels of stability, e.g. in[(PrO)(2)(CH3CO2)O](+), [(PrO)(4)(CH3CO2)O-2](+), [(TbO)(4)(CH3CO2)](+), [HO(CH3CO2)](+) and [(LaO)(malonate)O-4](+).
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | Inorganica Chimica Acta | ||||
Publisher: | ELSEVIER SCIENCE SA LAUSANNE | ||||
ISSN: | 0020-1693 | ||||
Official Date: | October 1995 | ||||
Dates: |
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Volume: | 238 | ||||
Number: | 1-2 | ||||
Number of Pages: | 6 | ||||
Page Range: | pp. 109-114 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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