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COBALT-MEDIATED FREE-RADICAL POLYMERIZATION OF ACRYLIC-MONOMERS
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UNSPECIFIED (1995) COBALT-MEDIATED FREE-RADICAL POLYMERIZATION OF ACRYLIC-MONOMERS. TRENDS IN POLYMER SCIENCE, 3 (11). pp. 365-373.
Research output not available from this repository, contact author.Abstract
The use of square-planar low-spin cobalt complexes to control the free-radical polymerization of vinyl monomers is described. The control exerted depends on both the catalyst and the monomer structure. Monomers with a beta-hydrogen (for example, methacrylates) undergo catalytic chain transfer, which is a powerful synthetic technique for producing macromonomers. Monomers without a beta-hydrogen (for example, acrylates) are capable of pseudo-living polymerization by exploitation of the 'persistent radical' effect. The structure of the cobalt complex is shown to be very important in determining its catalytic activity.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Journal or Publication Title: | TRENDS IN POLYMER SCIENCE | ||||
| Publisher: | ELSEVIER SCI LTD | ||||
| ISSN: | 0966-4793 | ||||
| Official Date: | November 1995 | ||||
| Dates: |
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| Volume: | 3 | ||||
| Number: | 11 | ||||
| Number of Pages: | 9 | ||||
| Page Range: | pp. 365-373 | ||||
| Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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