The Library
COBALT-MEDIATED FREE-RADICAL POLYMERIZATION OF ACRYLIC-MONOMERS
Tools
UNSPECIFIED (1995) COBALT-MEDIATED FREE-RADICAL POLYMERIZATION OF ACRYLIC-MONOMERS. TRENDS IN POLYMER SCIENCE, 3 (11). pp. 365-373. ISSN 0966-4793.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Abstract
The use of square-planar low-spin cobalt complexes to control the free-radical polymerization of vinyl monomers is described. The control exerted depends on both the catalyst and the monomer structure. Monomers with a beta-hydrogen (for example, methacrylates) undergo catalytic chain transfer, which is a powerful synthetic technique for producing macromonomers. Monomers without a beta-hydrogen (for example, acrylates) are capable of pseudo-living polymerization by exploitation of the 'persistent radical' effect. The structure of the cobalt complex is shown to be very important in determining its catalytic activity.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TRENDS IN POLYMER SCIENCE | ||||
Publisher: | ELSEVIER SCI LTD | ||||
ISSN: | 0966-4793 | ||||
Official Date: | November 1995 | ||||
Dates: |
|
||||
Volume: | 3 | ||||
Number: | 11 | ||||
Number of Pages: | 9 | ||||
Page Range: | pp. 365-373 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |