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MOLYBDOTUNGSTOVANADATES [V2MONW(4-N)O19](4-)
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UNSPECIFIED (1995) MOLYBDOTUNGSTOVANADATES [V2MONW(4-N)O19](4-). JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (17). pp. 2891-2893. ISSN 0300-9246.
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Abstract
The complete series of hexametalate anions [V2MonW(4-n)O-19](4-), with the two vanadiums cis and n = 0-4, has been identified in aqueous solution by V-51 NMR spectroscopy. The vanadium shifts and the pK(a) values both increase with increasing substitution of Mo for W. They correlate well with semiquantitative models, showing that somewhat greater changes arise from substitutions taking place in the V2O9 plane. A consistent preference is also found for like metal atoms to lie mutually cis.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0300-9246 | ||||
Official Date: | 7 September 1995 | ||||
Dates: |
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Number: | 17 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 2891-2893 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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