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HALIDE ABSTRACTION FROM [(ETA(5)-C5H5)NBCL4] LEADING TO NOVEL CATIONIC NIOBIUM(V) SPECIES - CRYSTAL-STRUCTURE OF THE DOUBLE HEXACHLOROANTIMONATE(V) SALT [(ETA(5)-C5H5)NBCL(MECN)(4)](3+)[(ETA(5)-C5H5)NB(MECN)(6)](4+)[SBCL6](7)CENTER-DOT-7MECN
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UNSPECIFIED (1994) HALIDE ABSTRACTION FROM [(ETA(5)-C5H5)NBCL4] LEADING TO NOVEL CATIONIC NIOBIUM(V) SPECIES - CRYSTAL-STRUCTURE OF THE DOUBLE HEXACHLOROANTIMONATE(V) SALT [(ETA(5)-C5H5)NBCL(MECN)(4)](3+)[(ETA(5)-C5H5)NB(MECN)(6)](4+)[SBCL6](7)CENTER-DOT-7MECN. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (23). pp. 2721-2722.
Research output not available from this repository, contact author.Abstract
Sequential removal of chloride ions from [(eta(5)-C5H5)NbCl4] can be realised using antimony(v) chloride in acetonitrile under controlled stoichiometry; the formation and structural characterisation of the novel Nb(v) cations [(eta(5)-C5H5)NbCl(MeCN)(4)](3+) and ([eta(5)-C5H5)Nb(MeCN)(6)](4+) are described.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | ||||
| Publisher: | ROYAL SOC CHEMISTRY | ||||
| ISSN: | 0022-4936 | ||||
| Official Date: | 7 December 1994 | ||||
| Dates: |
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| Number: | 23 | ||||
| Number of Pages: | 2 | ||||
| Page Range: | pp. 2721-2722 | ||||
| Publication Status: | Published |
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