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HALIDE ABSTRACTION FROM [(ETA(5)-C5H5)NBCL4] LEADING TO NOVEL CATIONIC NIOBIUM(V) SPECIES - CRYSTAL-STRUCTURE OF THE DOUBLE HEXACHLOROANTIMONATE(V) SALT [(ETA(5)-C5H5)NBCL(MECN)(4)](3+)[(ETA(5)-C5H5)NB(MECN)(6)](4+)[SBCL6](7)CENTER-DOT-7MECN

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UNSPECIFIED (1994) HALIDE ABSTRACTION FROM [(ETA(5)-C5H5)NBCL4] LEADING TO NOVEL CATIONIC NIOBIUM(V) SPECIES - CRYSTAL-STRUCTURE OF THE DOUBLE HEXACHLOROANTIMONATE(V) SALT [(ETA(5)-C5H5)NBCL(MECN)(4)](3+)[(ETA(5)-C5H5)NB(MECN)(6)](4+)[SBCL6](7)CENTER-DOT-7MECN. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (23). pp. 2721-2722.

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Abstract

Sequential removal of chloride ions from [(eta(5)-C5H5)NbCl4] can be realised using antimony(v) chloride in acetonitrile under controlled stoichiometry; the formation and structural characterisation of the novel Nb(v) cations [(eta(5)-C5H5)NbCl(MeCN)(4)](3+) and ([eta(5)-C5H5)Nb(MeCN)(6)](4+) are described.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
Publisher: ROYAL SOC CHEMISTRY
ISSN: 0022-4936
Official Date: 7 December 1994
Dates:
DateEvent
7 December 1994UNSPECIFIED
Number: 23
Number of Pages: 2
Page Range: pp. 2721-2722
Publication Status: Published

Data sourced from Thomson Reuters' Web of Knowledge

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