The Library
1,4,7-TRIS(2,2'-BIPYRIDYL-5-YLMETHYL)-1,4,7-TRIAZACYCLONONANE (L(1)), A POWERFUL TRIS(2,2'-BIPYRIDYL) CHELATING MACROCYCLIC LIGAND - X-RAY STRUCTURE OF [RU(L(1)H)][PF6](3), A COMPLEX CONTAINING A STRONGLY TRAPPED PROTON
Tools
Tools
Tools
UNSPECIFIED (1994) 1,4,7-TRIS(2,2'-BIPYRIDYL-5-YLMETHYL)-1,4,7-TRIAZACYCLONONANE (L(1)), A POWERFUL TRIS(2,2'-BIPYRIDYL) CHELATING MACROCYCLIC LIGAND - X-RAY STRUCTURE OF [RU(L(1)H)][PF6](3), A COMPLEX CONTAINING A STRONGLY TRAPPED PROTON. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (21). pp. 2489-2490. ISSN 0022-4936
Full text not available from this repository.Abstract
A new powerful tris(2,2'-bipyridyl) chelating ligand, 1,4,7-tris(2,2'-bipyridyl-5-ylmethyl)1,4,7-triazacyclononane (L(1)), has been synthesised and characterised, and an X-ray structure of [Ru(L(1)H)](3+) obtained; in the complex all three bipyridyl groups are coordinated, with a fairly regular octahedral Ru-II geometry, and although the azamacrocyclic nitrogen-atoms are non-coordinating to Ru-II, in aqueous solution they trap a single proton in the cavity between the macrocycle and the Ru-II, and which cannot be removed even at high pH.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 0022-4936 |
| Date: | 7 November 1994 |
| Number: | 21 |
| Number of Pages: | 2 |
| Page Range: | pp. 2489-2490 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/20201 |
Data sourced from Thomson Reuters' Web of Knowledge
Actions (login required)
 |
View Item |
