Skip to content Skip to navigation
University of Warwick
  • Study
  • |
  • Research
  • |
  • Business
  • |
  • Alumni
  • |
  • News
  • |
  • About

University of Warwick
Publications service & WRAP

Highlight your research

  • WRAP
    • Home
    • Search WRAP
    • Browse by Warwick Author
    • Browse WRAP by Year
    • Browse WRAP by Subject
    • Browse WRAP by Department
    • Browse WRAP by Funder
    • Browse Theses by Department
  • Publications Service
    • Home
    • Search Publications Service
    • Browse by Warwick Author
    • Browse Publications service by Year
    • Browse Publications service by Subject
    • Browse Publications service by Department
    • Browse Publications service by Funder
  • Help & Advice
University of Warwick

The Library

  • Login
  • Admin

REACTIONS OF 1,4,7-TRITHIACYCLONANE, [9]ANES3, WITH EARLY TRANSITION-METAL HALIDES - SYNTHESIS AND X-RAY STRUCTURE OF (FE([9]ANES3)2)[SB2CL8]

Tools
- Tools
+ Tools

UNSPECIFIED (1994) REACTIONS OF 1,4,7-TRITHIACYCLONANE, [9]ANES3, WITH EARLY TRANSITION-METAL HALIDES - SYNTHESIS AND X-RAY STRUCTURE OF (FE([9]ANES3)2)[SB2CL8]. TRANSITION METAL CHEMISTRY, 19 (2). pp. 187-190.

Research output not available from this repository, contact author.

Request Changes to record.

Abstract

The reactions of titanium(III) and (IV) chlorides with the crown thioether [9]aneS3 were investigated. [TiCl3(MeCN)3] gives a purple 1:1 adduct with a proposed octahedral structure involving tridentate fac-attachment of the ligand. With [TiCl4(MeCN)2] the identity of the yellow 1:1 adduct obtained is discussed in terms of a six-coordinate species with bidentate ligand chelation. The title compound was isolated from the reactions of [9]aneS3 with [TiCl3(MeCN)3][SbCl6] (by accident) and iron filings/SbCl5 in MeCN solution and characterised crystallographically. The cation has two macrocyclic ligands coordinated facially to a six-coordinate Fe2+ ion; the anion comprises dimeric [(SbCl4)2] units linked together into a polymeric chain by weak halogen bridging.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: TRANSITION METAL CHEMISTRY
Publisher: CHAPMAN HALL LTD
ISSN: 0340-4285
Official Date: April 1994
Dates:
DateEvent
April 1994UNSPECIFIED
Volume: 19
Number: 2
Number of Pages: 4
Page Range: pp. 187-190
Publication Status: Published

Data sourced from Thomson Reuters' Web of Knowledge

Request changes or add full text files to a record

Repository staff actions (login required)

View Item View Item
twitter

Email us: wrap@warwick.ac.uk
Contact Details
About Us