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REACTIONS OF 1,4,7-TRITHIACYCLONANE, [9]ANES3, WITH EARLY TRANSITION-METAL HALIDES - SYNTHESIS AND X-RAY STRUCTURE OF (FE([9]ANES3)2)[SB2CL8]
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UNSPECIFIED (1994) REACTIONS OF 1,4,7-TRITHIACYCLONANE, [9]ANES3, WITH EARLY TRANSITION-METAL HALIDES - SYNTHESIS AND X-RAY STRUCTURE OF (FE([9]ANES3)2)[SB2CL8]. TRANSITION METAL CHEMISTRY, 19 (2). pp. 187-190.
Research output not available from this repository, contact author.Abstract
The reactions of titanium(III) and (IV) chlorides with the crown thioether [9]aneS3 were investigated. [TiCl3(MeCN)3] gives a purple 1:1 adduct with a proposed octahedral structure involving tridentate fac-attachment of the ligand. With [TiCl4(MeCN)2] the identity of the yellow 1:1 adduct obtained is discussed in terms of a six-coordinate species with bidentate ligand chelation. The title compound was isolated from the reactions of [9]aneS3 with [TiCl3(MeCN)3][SbCl6] (by accident) and iron filings/SbCl5 in MeCN solution and characterised crystallographically. The cation has two macrocyclic ligands coordinated facially to a six-coordinate Fe2+ ion; the anion comprises dimeric [(SbCl4)2] units linked together into a polymeric chain by weak halogen bridging.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Journal or Publication Title: | TRANSITION METAL CHEMISTRY | ||||
| Publisher: | CHAPMAN HALL LTD | ||||
| ISSN: | 0340-4285 | ||||
| Official Date: | April 1994 | ||||
| Dates: |
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| Volume: | 19 | ||||
| Number: | 2 | ||||
| Number of Pages: | 4 | ||||
| Page Range: | pp. 187-190 | ||||
| Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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