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MONOCHLOROINDIUM DERIVATIVE OF TMTAA (DIBENZOTETRAMETHYLTETRAAZA[14]ANNULENE), [IN(C22H22N4)CL]
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UNSPECIFIED (1994) MONOCHLOROINDIUM DERIVATIVE OF TMTAA (DIBENZOTETRAMETHYLTETRAAZA[14]ANNULENE), [IN(C22H22N4)CL]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 50 (Part 7). pp. 1072-1074.
Research output not available from this repository, contact author.Abstract
The structure consists of an InCl fragment bonded symmetrically to the four N atoms of the macrocyclic ligand tmtaa (chloro{3,5,14,16-tetramethyl-2,6,13,17-tetraaza-tricyclo[16.4.0.0(7,12)]docosa-1(18),2,5,7(12),8,10,13,16,-19,21-decaenediido-N,N,N'',N'''}indium). This is the first structural characterization of an In entity coordinated to this ligand and reveals an unusual five-coordinate square-pyramidal geometry around the In atom. The metal is displaced 0.738 (3) angstrom above the N4 coordination plane. The average In-N bond distance is 2.165 (5) angstrom and the In-Cl distance is 2.380 angstrom.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Journal or Publication Title: | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | ||||
| Publisher: | MUNKSGAARD INT PUBL LTD | ||||
| ISSN: | 0108-2701 | ||||
| Official Date: | 15 July 1994 | ||||
| Dates: |
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| Volume: | 50 | ||||
| Number: | Part 7 | ||||
| Number of Pages: | 3 | ||||
| Page Range: | pp. 1072-1074 | ||||
| Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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