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LOW-TEMPERATURE SYNTHESIS OF A BISMUTH VANADIUM-OXIDE ISOMORPHOUS WITH GAMMA-BI4V2O11
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UNSPECIFIED (1994) LOW-TEMPERATURE SYNTHESIS OF A BISMUTH VANADIUM-OXIDE ISOMORPHOUS WITH GAMMA-BI4V2O11. SOLID STATE COMMUNICATIONS, 91 (5). pp. 357-360. ISSN 0038-1098
Full text not available from this repository.Abstract
A bismuth vanadium oxide has been synthesised from bismuth nitrate hydrate and ammonium metavanadate using a novel room-temperature precipitation technique. The material is amorphous at room temperature and becomes fully crystalline at 593K This crystalline phase is stable at room temperature. X-ray fluorescence and thermogravimetric studies showed that the compound has a chemical formula Bi4V2.1O11.2. Powder X-ray diffraction showed that the phase is isomorphous with the gamma-Bi4V2O11 phase that has previously only been seen at temperatures above 840K. The unit cell is body centred tetragonal with a = 3.934(2) angstrom and c = 15.37(1) angstrom.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QC Physics |
| Journal or Publication Title: | SOLID STATE COMMUNICATIONS |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| ISSN: | 0038-1098 |
| Date: | August 1994 |
| Volume: | 91 |
| Number: | 5 |
| Number of Pages: | 4 |
| Page Range: | pp. 357-360 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/20530 |
Data sourced from Thomson Reuters' Web of Knowledge
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