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ENERGETICS OF THE TETRACHLOROPHOSPHONIUM CATION, PCL4(-),G, THE HEXACHLOROPHOSPHATE ANION, PCL6(-),G AND METASTABLE PHOSPHORUS (V) CHLORIDE [PCL4(+)]2[PCL6(-)][CL-],C
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UNSPECIFIED (1994) ENERGETICS OF THE TETRACHLOROPHOSPHONIUM CATION, PCL4(-),G, THE HEXACHLOROPHOSPHATE ANION, PCL6(-),G AND METASTABLE PHOSPHORUS (V) CHLORIDE [PCL4(+)]2[PCL6(-)][CL-],C. [Journal Item]
Full text not available from this repository.Abstract
Lattice potential energy calculations made on [PCl4+]2[PCl6-][Cl-] lead to an estimate of the lattice energy of this metastable phase of phosphorus (V) chloride to be 956 kJ mol-1 (corresponding to 319 kJ mol-1 per PCl5 formula unit). The known stability characteristics of alkali metal hexachlorophosphates enable the estimation of the enthalpy of formation of PCl6-, g to be in the range: -908 less-than-or-equal-to DELTA(f)H0(PCl6-, g) less-than-or-equal-to -896 kJ mol-1, similarly, +397 kJ mol-1 greater-than-or-equal-to DELTA(f)H0(PCl4+, g) greater-than-or-equal-to + 391 kJ mol-1.
| Item Type: | Journal Item |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | POLYHEDRON |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| ISSN: | 0277-5387 |
| Date: | May 1994 |
| Volume: | 13 |
| Number: | 9 |
| Number of Pages: | 2 |
| Page Range: | pp. 1481-1482 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/20626 |
Data sourced from Thomson Reuters' Web of Knowledge
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