The Library
ENERGETICS OF THE TETRACHLOROPHOSPHONIUM CATION, PCL4(-),G, THE HEXACHLOROPHOSPHATE ANION, PCL6(-),G AND METASTABLE PHOSPHORUS (V) CHLORIDE [PCL4(+)]2[PCL6(-)][CL-],C
Tools
UNSPECIFIED (1994) ENERGETICS OF THE TETRACHLOROPHOSPHONIUM CATION, PCL4(-),G, THE HEXACHLOROPHOSPHATE ANION, PCL6(-),G AND METASTABLE PHOSPHORUS (V) CHLORIDE [PCL4(+)]2[PCL6(-)][CL-],C. POLYHEDRON, 13 (9). pp. 1481-1482.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Abstract
Lattice potential energy calculations made on [PCl4+]2[PCl6-][Cl-] lead to an estimate of the lattice energy of this metastable phase of phosphorus (V) chloride to be 956 kJ mol-1 (corresponding to 319 kJ mol-1 per PCl5 formula unit). The known stability characteristics of alkali metal hexachlorophosphates enable the estimation of the enthalpy of formation of PCl6-, g to be in the range: -908 less-than-or-equal-to DELTA(f)H0(PCl6-, g) less-than-or-equal-to -896 kJ mol-1, similarly, +397 kJ mol-1 greater-than-or-equal-to DELTA(f)H0(PCl4+, g) greater-than-or-equal-to + 391 kJ mol-1.
Item Type: | Journal Item | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | POLYHEDRON | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0277-5387 | ||||
Official Date: | May 1994 | ||||
Dates: |
|
||||
Volume: | 13 | ||||
Number: | 9 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 1481-1482 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |