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AN NMR-STUDY ON THE LIQUID CESIUM OXYGEN SYSTEM - THE STATE OF OXYGEN AND IONIC ASSOCIATION IN THE METALLIC REGIME

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UNSPECIFIED (1994) AN NMR-STUDY ON THE LIQUID CESIUM OXYGEN SYSTEM - THE STATE OF OXYGEN AND IONIC ASSOCIATION IN THE METALLIC REGIME. JOURNAL OF PHYSICS-CONDENSED MATTER, 6 (21). pp. 3889-3898.

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Abstract

The liquid caesium-oxygen system in the metallic regime has been investigated by the NMR technique. Measurements were made of the Knight shift for both Cs-133 and O-17 nuclei, and the nuclear relaxation time, T1, for the latter. The Knight shift for Cs-133 nuclei decreases almost linearly up to 25 at.% of O and further decreases with a steeper slope to the value in Cs2O, while the shift for O-17 nuclei is almost independent of the composition up to 21 at.%. The analysis of T1 suggests that the gradient of the electrostatic field coupled with the nuclear quadrupole moment of O-17 is also insensitive to the composition. The results are discussed with particular reference to the state of the 0 atoms and possible ionic association in the liquid Cs-O system in the metallic regime.

Item Type: Journal Article
Subjects: Q Science > QC Physics
Journal or Publication Title: JOURNAL OF PHYSICS-CONDENSED MATTER
Publisher: IOP PUBLISHING LTD
ISSN: 0953-8984
Official Date: 23 May 1994
Dates:
DateEvent
23 May 1994UNSPECIFIED
Volume: 6
Number: 21
Number of Pages: 10
Page Range: pp. 3889-3898
Publication Status: Published

Data sourced from Thomson Reuters' Web of Knowledge

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