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STUDIES OF PENDANT-ARM MACROCYCLIC LIGANDS .8. SYNTHESIS OF 2 PENTAAZAMACROCYCLES BASED UPON PYRIDINE-CONTAINING TETRAAZAMACROCYCLES WITH A SINGLE PENDANT COORDINATING 2-PYRIDYLMETHYL ARM, AND CHARACTERIZATION OF THEIR NICKEL(II), COPPER(II) AND ZINC(II) COMPLEXES - CRYSTAL-STRUCTURE OF 7-(2'-PYRIDYLMETHYL)-3,7,11,17-TETRAAZABICYCLO[11.3.1]HEPTADECA-1(17),13,15-TRIENEZINC(II) TETRAFLUOROBORATE
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UNSPECIFIED (1994) STUDIES OF PENDANT-ARM MACROCYCLIC LIGANDS .8. SYNTHESIS OF 2 PENTAAZAMACROCYCLES BASED UPON PYRIDINE-CONTAINING TETRAAZAMACROCYCLES WITH A SINGLE PENDANT COORDINATING 2-PYRIDYLMETHYL ARM, AND CHARACTERIZATION OF THEIR NICKEL(II), COPPER(II) AND ZINC(II) COMPLEXES - CRYSTAL-STRUCTURE OF 7-(2'-PYRIDYLMETHYL)-3,7,11,17-TETRAAZABICYCLO[11.3.1]HEPTADECA-1(17),13,15-TRIENEZINC(II) TETRAFLUOROBORATE. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (4). pp. 485-489. ISSN 0300-9246
Full text not available from this repository.Abstract
Two new quinquedentate pentaazamacrocycles, 7-(2'-pyridylmethyl)-3,7,11,17-tetraazabicyclo-[11.3.1]heptadeca-1(17),13,15-tr iene L1 and its 3,11-dimethyl derivative L2, have been characterised, together with their metal complexes of formulae [ML(OH2)] [BF4]2 (M = Ni or Cu) and [ZnL] [BF4]2 (L = L1 or L2) . The crystal structure of [ZnL1][BF4]2 shows a distorted square-pyramidal geometry, with the Zn 0.59 angstrom above the plane of the macrocyclic ring in the direction of the pendant co-ordinated pyridyl group.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 0300-9246 |
| Date: | 21 February 1994 |
| Number: | 4 |
| Number of Pages: | 5 |
| Page Range: | pp. 485-489 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/20818 |
Data sourced from Thomson Reuters' Web of Knowledge
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