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BIS(ETA(5)-TERT-BUTYLCYCLOPENTADIENYL)DICHLORONIOBIUM(IV)
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UNSPECIFIED. (1994) BIS(ETA(5)-TERT-BUTYLCYCLOPENTADIENYL)DICHLORONIOBIUM(IV). ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 50 (Part 1). pp. 33-36. ISSN 0108-2701
Full text not available from this repository.Abstract
The monomeric molecule of the title compound, [NbCl2-(C9H13)2], is best described as a paramagnetic pseudo-tetrahedral complex of niobium(IV). The two tert-butylcyclopentadienyl ligands are asymmetrically bound to the Nb atom [Nb-C bond-length range 2.394 (6)-2.470 (6) angstrom]. The asymmetry is accounted for in terms of the steric demand of the (t)Bu groups and Cl ligands. Pseudo-tetrahedral geometry is completed by two Cl ligands [Nb-Cl 2.477 (2) and 2.483 (2) angstrom, Cl-Nb-Cl 84.15 (6)-degrees].
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS |
| Publisher: | MUNKSGAARD INT PUBL LTD |
| ISSN: | 0108-2701 |
| Date: | 15 January 1994 |
| Volume: | 50 |
| Number: | Part 1 |
| Number of Pages: | 4 |
| Page Range: | pp. 33-36 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/20872 |
Data sourced from Thomson Reuters' Web of Knowledge
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