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O-17 SATELLITE TRANSITION SPECTROSCOPY OF AMORPHOUS SIO2

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UNSPECIFIED (1993) O-17 SATELLITE TRANSITION SPECTROSCOPY OF AMORPHOUS SIO2. [Journal Item]

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Abstract

The increase of spectral resolution of the 3/2 <--> 1/2 (-1/2 <--> -3/2) satellite transition spinning sidebands of O-17 NMR has been demonstrated for amorphous SiO2. Even for large quadrupole coupling constants (C(Q) almost-equal-to 5 MHz), the spinning sidebands can be observed. Compared with the static lineshape, there is a line narrowing of greater than ten; the additional gain in resolution is three with respect to the central transition magic angle spinning (MAS) pattern. This effect can be used for improved determination of the true chemical shifts under MAS conditions.

Item Type: Journal Item
Subjects: T Technology > TP Chemical technology
T Technology > TA Engineering (General). Civil engineering (General)
Journal or Publication Title: JOURNAL OF NON-CRYSTALLINE SOLIDS
Publisher: ELSEVIER SCIENCE BV
ISSN: 0022-3093
Date: March 1993
Volume: 155
Number: 1
Number of Pages: 4
Page Range: pp. 95-98
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/21479

Data sourced from Thomson Reuters' Web of Knowledge

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