The Library
SYNTHESIS AND REACTIVITY OF BIS(ETA-1,4-DI-TERT-BUTYLBUTA-1,3-DIENE)COBALT - THE X-RAY CRYSTAL-STRUCTURE OF THE ANIONIC BUTADIENE SANDWICH COMPLEX [K(18-CROWN-6)(THF)2] [CO(ETA-C4H4BUT2)2]
Tools
Tools
Tools
UNSPECIFIED (1993) SYNTHESIS AND REACTIVITY OF BIS(ETA-1,4-DI-TERT-BUTYLBUTA-1,3-DIENE)COBALT - THE X-RAY CRYSTAL-STRUCTURE OF THE ANIONIC BUTADIENE SANDWICH COMPLEX [K(18-CROWN-6)(THF)2] [CO(ETA-C4H4BUT2)2]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (3). pp. 248-250. ISSN 0022-4936
Full text not available from this repository.Abstract
Cocondensation of cobalt atoms with 1,4-di-tert-butylbuta-1,3-diene affords the stable, paramagnetic butadiene sandwich compound [Co(eta-C4H4But2)2], which is a reactive source of Co0 fragments; reduction Of [Co(eta-C4H4But2)2] with potassium affords the first crystallographically characterised homoleptic butadiene sandwich complex, [Co(eta-C4H4But2)2]-, in which the bonding is that of a genuine diene rather than a metallacyclopentene.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS |
| Publisher: | ROYAL SOC CHEMISTRY |
| ISSN: | 0022-4936 |
| Date: | 7 February 1993 |
| Number: | 3 |
| Number of Pages: | 3 |
| Page Range: | pp. 248-250 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/21540 |
Data sourced from Thomson Reuters' Web of Knowledge
Actions (login required)
 |
View Item |
