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THRESHOLD FLUENCES FOR PRODUCTION OF POSITIVE AND NEGATIVE-IONS IN MATRIX-ASSISTED LASER DESORPTION IONIZATION USING LIQUID AND SOLID MATRICES

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UNSPECIFIED (1993) THRESHOLD FLUENCES FOR PRODUCTION OF POSITIVE AND NEGATIVE-IONS IN MATRIX-ASSISTED LASER DESORPTION IONIZATION USING LIQUID AND SOLID MATRICES. CHEMICAL PHYSICS LETTERS, 202 (1-2). pp. 93-100. ISSN 0009-2614

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Abstract

Dependences of positive and negative analyte-ion and matrix-ion signals upon pulse energy (at 266 nm) have been measured in matrix-assisted laser desorption/ionization (MALDI), for a liquid matrix (3-nitrobenzyl alcohol) and for a solid matrix (sinapinic acid). The analyte was the protein bovine insulin. The results suggest that the threshold fluences for the formation of positive and of negative ions are the same as each other, for a given matrix. The threshold fluences are lower in the case of the liquid matrix as compared to the solid matrix.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Q Science > QC Physics
Journal or Publication Title: CHEMICAL PHYSICS LETTERS
Publisher: ELSEVIER SCIENCE BV
ISSN: 0009-2614
Date: 15 January 1993
Volume: 202
Number: 1-2
Number of Pages: 8
Page Range: pp. 93-100
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/21589

Data sourced from Thomson Reuters' Web of Knowledge

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