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CRYSTAL-STRUCTURE OF AN ANTIFERROMAGNETICALLY COUPLED MU-CARBONATO-BRIDGED DINICKEL(II) COMPLEX CONTAINING THE PENDENT-ARM MACROCYCLE 1-(3-DIMETHYLAMINOPROPYL)-1,5,9-TRIAZACYCLODODECANE (L(1)) - A SYSTEM WHICH READILY SEQUESTERS CARBON-DIOXIDE FROM AIR
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UNSPECIFIED (1992) CRYSTAL-STRUCTURE OF AN ANTIFERROMAGNETICALLY COUPLED MU-CARBONATO-BRIDGED DINICKEL(II) COMPLEX CONTAINING THE PENDENT-ARM MACROCYCLE 1-(3-DIMETHYLAMINOPROPYL)-1,5,9-TRIAZACYCLODODECANE (L(1)) - A SYSTEM WHICH READILY SEQUESTERS CARBON-DIOXIDE FROM AIR. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (23). pp. 1701-1703. ISSN 0022-4936.
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Abstract
The nickel(II) complex of the pendent-arm macrocycle 1-(3-dimethylaminopropyl)-1,5,9-triazacyclododecane (L1) sequesters CO2 from air to yield, after addition of thiocyanate ion, [{(HL1)Ni(NCS)}2(CO3)]2+, the first example of a mu-carbonato dinickel(II) complex; the Ni atoms are antiferromagnetically coupled with the exceptionally large exchange constant -2J = 94.6 +/- 0.4 cm-1.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0022-4936 | ||||
Official Date: | 1 December 1992 | ||||
Dates: |
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Number: | 23 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 1701-1703 | ||||
Publication Status: | Published |
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