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SYNTHESIS AND REACTIVITY OF RUTHENATETRABORANES - MOLECULAR-STRUCTURE OF [RUH(B3H8)(CO)(PPH3)2]
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UNSPECIFIED (1992) SYNTHESIS AND REACTIVITY OF RUTHENATETRABORANES - MOLECULAR-STRUCTURE OF [RUH(B3H8)(CO)(PPH3)2]. INORGANIC CHEMISTRY, 31 (22). pp. 4606-4610. ISSN 0020-1669.
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Abstract
The reactions of [RuClH(CO)(PPh3)3] and [RuH(CO)(NCMe)2(PPh3)2]ClO4 with [NMe4][B3H8] provide the ruthenatetraborane [RuH(B3H8)(CO)(PPh3)2] [Crystallographically characterized: monoclinic crystals of space group P2(1)/c (Z = 4), in a unit cell of dimensions a = 14.424 (5) angstrom, b = 10.628 (4) angstrom, c = 22.987 (9) angstrom, and beta = 97.86 (3)-degrees]. The integrity of the RuB3 moiety is retained in the reactions with N-halosuccinimides, leading to the halo derivatives [RuX(B3H8)(CO)(PPh3)2] (X = Cl, Br, 1); however, reaction of the bromo derivative with Na[S2CNMe2] leads to rupture of the metallatetraborane and formation of [Ru(S2CNMe2)2(CO)(PPh3)].
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | INORGANIC CHEMISTRY | ||||
Publisher: | AMER CHEMICAL SOC | ||||
ISSN: | 0020-1669 | ||||
Official Date: | 28 October 1992 | ||||
Dates: |
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Volume: | 31 | ||||
Number: | 22 | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 4606-4610 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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