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RUTHENATETRABORANES - SYNTHESIS OF [RU(B3H8)(PPH3)(HB(PZ)3)] AND CRYSTAL-STRUCTURE OF [RUCL(PPH3)2(HB(PZ)3)] (PZ = PYRAZOL-1-YL)

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UNSPECIFIED (1992) RUTHENATETRABORANES - SYNTHESIS OF [RU(B3H8)(PPH3)(HB(PZ)3)] AND CRYSTAL-STRUCTURE OF [RUCL(PPH3)2(HB(PZ)3)] (PZ = PYRAZOL-1-YL). INORGANIC CHEMISTRY, 31 (13). pp. 2906-2908. ISSN 0020-1669

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Abstract

The reaction of [RuCl2(PPh3)3] with K[HB(pz)3] (pz = pyrazol-1-yl) affords [RuCl(PPhl)2{kappa-3-HB(pz)3}] [crystallographically characterized with monoclinic crystals of space group P2(1)/a, Z = 8, in a unit cell of dimensions a = 19.75 (1) angstrom, b = 22.48 (1) angstrom, c = 20.283 (7) angstrom, and beta = 112.94 (3)-degrees], which upon treatment with NR4[B3H8] (R = Me, Bu) provides the ruthenatetraborane [Ru(B3H8)(PPh3){kappa-3-HB(pz)3}].

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: INORGANIC CHEMISTRY
Publisher: AMER CHEMICAL SOC
ISSN: 0020-1669
Date: 24 June 1992
Volume: 31
Number: 13
Number of Pages: 3
Page Range: pp. 2906-2908
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/21968

Data sourced from Thomson Reuters' Web of Knowledge

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