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STRUCTURAL RELATIONSHIPS DERIVED FROM THE ANALYSIS OF ELECTRON-SPIN-RESONANCE SPECTRA OF SOME TECHNETIUM COMPLEXES
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UNSPECIFIED (1992) STRUCTURAL RELATIONSHIPS DERIVED FROM THE ANALYSIS OF ELECTRON-SPIN-RESONANCE SPECTRA OF SOME TECHNETIUM COMPLEXES. Inorganica Chimica Acta, 193 (2). pp. 191-196. ISSN 0020-1693.
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Abstract
An extension of a method relating chemical structure to the ESR parameters A(parallel-to) and g(parallel-to) of paramagnetic technetium complexes is presented. Complexes having the same axial ligand lie in a narrow band of values of A(parallel-to) and g(parallel-to) such that Tc(II) nitrosyl and thionitrosyl complexes have distinctly different ESR parameters to Tc(VI) nitrido and oxo complexes. Thus the ESR spectrum of a solution resulting from a reaction where the nature of the product is in some doubt can be used to identify the oxidation state, the nature of the axial ligand and possible equatorial ligands.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | Inorganica Chimica Acta | ||||
Publisher: | ELSEVIER SCIENCE SA LAUSANNE | ||||
ISSN: | 0020-1693 | ||||
Official Date: | 16 March 1992 | ||||
Dates: |
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Volume: | 193 | ||||
Number: | 2 | ||||
Number of Pages: | 6 | ||||
Page Range: | pp. 191-196 | ||||
Publication Status: | Published |
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