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ORGANOMETALLIC MACROCYCLE CHEMISTRY .1. THE REACTIONS OF [RUCL2(PPH3)3] WITH 1,4,7-TRITHIACYCLONONANE AND 1,4,8,11-TETRATHIACYCLOTETRADECANE
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UNSPECIFIED (1992) ORGANOMETALLIC MACROCYCLE CHEMISTRY .1. THE REACTIONS OF [RUCL2(PPH3)3] WITH 1,4,7-TRITHIACYCLONONANE AND 1,4,8,11-TETRATHIACYCLOTETRADECANE. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 426 (2). C40-C43. ISSN 0022-328X
Full text not available from this repository.Abstract
The reactions of [RuCl2(PPh3)3] with the thiacrown ethers 1,4,7-trithiacyclononane (9-S3) and 1,4,8,11-tetrathiacyclotetradecane (14-S4) provide the crystallographically characterised complexes [RuCl2(PPh3)(9-S3)] and cis-[RuCl(PPh3)(14-S4)]+. The thiocarbonyl containing salts [RuCl(CS) (PPh3)(9-S3)]ClO4 and [RuH(CS)(PPh3)(9-S3)]ClO4 are obtained by treatment of the complexes [RuCl2(OH2)(CS)(PPh3)2] and [RuClH(CS)(PPh3)3] with 9-S3.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY |
| Publisher: | ELSEVIER SCIENCE SA LAUSANNE |
| ISSN: | 0022-328X |
| Date: | 17 March 1992 |
| Volume: | 426 |
| Number: | 2 |
| Number of Pages: | 4 |
| Page Range: | C40-C43 |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/22106 |
Data sourced from Thomson Reuters' Web of Knowledge
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