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SYNTHESIS AND REACTIVITY OF HYDRIDO, HALOGENO, AND SIGMA-ORGANYL RUTHENATETRABORANES - CRYSTAL-STRUCTURE OF [RUH(B3H8)(CO)(PPH3)2]
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UNSPECIFIED (1992) SYNTHESIS AND REACTIVITY OF HYDRIDO, HALOGENO, AND SIGMA-ORGANYL RUTHENATETRABORANES - CRYSTAL-STRUCTURE OF [RUH(B3H8)(CO)(PPH3)2]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 425 (1-2). C8-C10.
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Abstract
The reactions of [RuClR(CO)(PPh3)n] (n = 2, R = sigma-vinyl, sigma-aryl; n = 3, R = H) with NMe4[B3H8] provide the ruthenatetraboranes [RuR(B3H8)(CO)(PPh3)2]. The crystal structure was determined for the compound with R = H. The latter reacts with N-halogeno succinimides to give the halogeno derivatives [RuR(B3H8)(CO)(PPh3)2] (R = Cl, Br, I) and with tBuNC in dichloromethane to give [RuClH(CNtBu)2(PPh3)2]. Sodium dialkyldithiocarbamate displaces the B3H8 moiety from the halogeno derivatives, with formation of [Ru(S2CNMe2)2(CO)(PPh3)].
Item Type: | Journal Item | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY | ||||
Publisher: | ELSEVIER SCIENCE SA LAUSANNE | ||||
ISSN: | 0022-328X | ||||
Official Date: | 25 February 1992 | ||||
Dates: |
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Volume: | 425 | ||||
Number: | 1-2 | ||||
Number of Pages: | 3 | ||||
Page Range: | C8-C10 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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