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A H-1-NMR METHOD FOR THE DETERMINATION OF ENANTIOMERIC EXCESS AND ABSOLUTE-CONFIGURATION OF CIS-DIHYDRODIOL METABOLITES OF POLYCYCLIC ARENES AND HETEROARENES
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UNSPECIFIED (1992) A H-1-NMR METHOD FOR THE DETERMINATION OF ENANTIOMERIC EXCESS AND ABSOLUTE-CONFIGURATION OF CIS-DIHYDRODIOL METABOLITES OF POLYCYCLIC ARENES AND HETEROARENES. TETRAHEDRON LETTERS, 33 (9). pp. 1241-1244. ISSN 0040-4039.
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Abstract
Metabolism of benzofuran and 2,3-dihydrobenzofuran by P.putida UV4 each yielded cis-dihydrodiols; catalytic hydrogenation of the cis-dihydrodiols obtained from polycyclic arenes and azaarenes followed by diMTPA ester formation (using both R- and S-MTPA) on the cis-tetrahydrodiols formed the basis of a H-1-NMR method for the determination of both enantiomeric excess and absolute configuration.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TETRAHEDRON LETTERS | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0040-4039 | ||||
Official Date: | 25 February 1992 | ||||
Dates: |
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Volume: | 33 | ||||
Number: | 9 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 1241-1244 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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