The Library
STRUCTURE OF A COMPLEX OF 1,4,8,11-TETRAAZACYCLOTETRADECANE (CYCLAM) WITH ZINC(II) CHLORIDE
Tools
UNSPECIFIED (1992) STRUCTURE OF A COMPLEX OF 1,4,8,11-TETRAAZACYCLOTETRADECANE (CYCLAM) WITH ZINC(II) CHLORIDE. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 48 (Part 1). pp. 16-19. ISSN 0108-2701.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Abstract
Bis[mu-chloro-(1,4,8,11-tetraazacyclotetradecane)zinc(II)] tetrachlorozincate(II) hemihydrate, [ZnCl(C10H24N4)]2n.n[ZnCl4]2-.(n/2)H2O, M(r) = 818.5 for n = 1, tetragonal, 142dBAR, a = 17.950 (5), c = 10.907 (2) angstrom, V = 3514 (1) angstrom 3, Z = 4, D(m) = 1.52, D(x) = 1.55 g cm3, lambda(Mo K-alpha) - 0.71069 angstrom, mu = 25.7 cm-1, T = 290 K, R = 0.095 for 750 unique observed [I/sigma(I) greater-than-or-equal-to 2.0] reflections. The structure consists of infinite -Cl-[Zn(cyclam)]2+ -Cl- chains interspersed with [ZnCl4]2- ions. The mean Zn-N and Zn-Cl (chain) distances are 2.13 (1) and 2.730 (4) angstrom, while the Zn-Cl bond length in the anion is 2.288 (5) angstrom.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | ||||
Publisher: | MUNKSGAARD INT PUBL LTD | ||||
ISSN: | 0108-2701 | ||||
Official Date: | 15 January 1992 | ||||
Dates: |
|
||||
Volume: | 48 | ||||
Number: | Part 1 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 16-19 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |