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MICROHETEROGENEOUS CATALYSIS IN MODIFIED ELECTRODES .2. ELECTRON-TRANSFER MEDIATOR CATALYST COMPOSITES
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UNSPECIFIED (1991) MICROHETEROGENEOUS CATALYSIS IN MODIFIED ELECTRODES .2. ELECTRON-TRANSFER MEDIATOR CATALYST COMPOSITES. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 316 (1-2). pp. 1-22. ISSN 0022-0728.
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Abstract
Analytical expressions quantifying the transport and kinetics in polymer modified electrodes containing a homogeneous distribution of spherical microparticulate catalysts are presented. In particular the dependence of the flux on the number of catalytic particles per unit volume, the layer thickness, the substrate and mediator concentrations and the particle radius are outlined. A strategy for optimising the electrocatalytic behaviour of these multicomponent microheterogeneous systems is also outlined.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Subjects: | Q Science > QD Chemistry | ||||
| Journal or Publication Title: | JOURNAL OF ELECTROANALYTICAL CHEMISTRY | ||||
| Publisher: | ELSEVIER SCIENCE SA LAUSANNE | ||||
| ISSN: | 0022-0728 | ||||
| Official Date: | 25 October 1991 | ||||
| Dates: |
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| Volume: | 316 | ||||
| Number: | 1-2 | ||||
| Number of Pages: | 22 | ||||
| Page Range: | pp. 1-22 | ||||
| Publication Status: | Published |
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