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BIOTRANSFORMATIONS IN CARBOHYDRATE SYNTHESIS - N-ACETYLGALACTOSAMINYL AND N-ACETYLGLUCOSAMINYL TRANSFER ONTO METHYL ALPHA-GLUCOSIDES AND BETA-GLUCOSIDES CATALYZED BY THE BETA-N-ACETYLHEXOSAMINIDASE FROM ASPERGILLUS-ORYZAE
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UNSPECIFIED (1991) BIOTRANSFORMATIONS IN CARBOHYDRATE SYNTHESIS - N-ACETYLGALACTOSAMINYL AND N-ACETYLGLUCOSAMINYL TRANSFER ONTO METHYL ALPHA-GLUCOSIDES AND BETA-GLUCOSIDES CATALYZED BY THE BETA-N-ACETYLHEXOSAMINIDASE FROM ASPERGILLUS-ORYZAE. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (21). pp. 1550-1551. ISSN 0022-4936.
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Abstract
Regioselectivity of N-acetylhexosaminyl transfer onto methyl alpha- and beta-D-glucosides catalysed by the N-acetylhexosaminidase from Aspergillus oryzae is strongly dependent on the configuration at the anomeric centre of the acceptor: with the beta-glucoside, 1,3- and 1,4-transfer products are formed, whereas with the alpha-glucoside, 1,4- and 1,6-transfer products are obtained.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0022-4936 | ||||
Official Date: | 1 November 1991 | ||||
Dates: |
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Number: | 21 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 1550-1551 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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