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BIOTRANSFORMATIONS IN CARBOHYDRATE SYNTHESIS - N-ACETYLGALACTOSAMINYL AND N-ACETYLGLUCOSAMINYL TRANSFER ONTO METHYL ALPHA-GLUCOSIDES AND BETA-GLUCOSIDES CATALYZED BY THE BETA-N-ACETYLHEXOSAMINIDASE FROM ASPERGILLUS-ORYZAE

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UNSPECIFIED. (1991) BIOTRANSFORMATIONS IN CARBOHYDRATE SYNTHESIS - N-ACETYLGALACTOSAMINYL AND N-ACETYLGLUCOSAMINYL TRANSFER ONTO METHYL ALPHA-GLUCOSIDES AND BETA-GLUCOSIDES CATALYZED BY THE BETA-N-ACETYLHEXOSAMINIDASE FROM ASPERGILLUS-ORYZAE. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (21). pp. 1550-1551. ISSN 0022-4936

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Abstract

Regioselectivity of N-acetylhexosaminyl transfer onto methyl alpha- and beta-D-glucosides catalysed by the N-acetylhexosaminidase from Aspergillus oryzae is strongly dependent on the configuration at the anomeric centre of the acceptor: with the beta-glucoside, 1,3- and 1,4-transfer products are formed, whereas with the alpha-glucoside, 1,4- and 1,6-transfer products are obtained.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Journal or Publication Title: JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
Publisher: ROYAL SOC CHEMISTRY
ISSN: 0022-4936
Date: 1 November 1991
Number: 21
Number of Pages: 2
Page Range: pp. 1550-1551
Publication Status: Published
URI: http://wrap.warwick.ac.uk/id/eprint/22375

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